7.10 Acids, Bases And Salts

Acids, bases and salts find widespread occurrence in nature. Hydrochloric acid present in the gastric juice is secreted by the lining of our stomach in a significant amount of 1.2-1.5 L/day and is essential for digestive processes.

Acetic acid is known to be the main constituent of vinegar. Lemon and orange juices contain citric and ascorbic acids, and tartaric acid is found in tamarind paste. As most of the acids taste sour, the word “acid” has been derived from a latin word “acidus” meaning sour.

Acids are known to turn blue litmus paper into red and liberate dihydrogen on reacting with some metals. Similarly, bases are known to turn red litmus paper blue, taste bitter and feel soapy. A common example of a base is washing soda used for washing purposes.

When acids and bases are mixed in the right proportion they react with each other to give salts. Some commonly known examples of salts are sodium chloride, barium sulphate, sodium nitrate.

Sodium chloride (common salt ) is an important component of our diet and is formed by reaction between hydrochloric acid and sodium hydroxide.

It exists in solid state as a cluster of positively charged sodium ions and negatively charged chloride ions which are held together due to electrostatic interactions between oppositely charged species (Fig).

The electrostatic forces between two charges are inversely proportional to dielectric constant of the medium. Water, a universal solvent, possesses a very high dielectric constant of 80.

Thus, when sodium chloride is dissolved in water, the electrostatic interactions are reduced by a factor of 80 and this facilitates the ions to move freely in the solution. Also, they are well separated due to hydration with water molecules.

Comparing, the ionization of hydrochloric acid with that of acetic acid in water we find that though both of them are polar covalent molecules, former is completely ionized into its constituent ions, while the latter is only partially ionized (< 5%).

The extent to which ionization occurs depends upon the strength of the bond and the extent of solvation of ions produced. The terms dissociation and ionization have earlier been used with different meaning.

Dissociation refers to the process of separation of ions in water already existing as such in the solid state of the solute, as in sodium chloride.

On the other hand, ionization corresponds to a process in which a neutral molecule splits into charged ions in the solution. Here, we shall not distinguish between the two and use the two terms interchangeably.

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