6.1.3 The State of the System

The system must be described in order to make any useful calculations by specifying quantitatively each of the properties such as its pressure (p), volume (V), and temperature (T ) as well as the composition of the system.

We need to describe the system by specifying it before and after the change. You would recall from your Physics course that the state of a system in mechanics is completely specified at a given instant of time, by the position and velocity of each mass point of the system.

In thermodynamics, a different and much simpler concept of the state of a system is introduced. It does not need detailed knowledge of motion of each particle because, we deal with average measurable properties of the system. We specify the state of the system by state functions or state variables.

The state of a thermodynamic system is described by its measurable or macroscopic (bulk) properties. We can describe the state of a gas by quoting its pressure (p), volume (V), temperature (T ), amount (n) etc.

Variables like p, V, T are called state variables or state functions because their values depend only on the state of the system and not on how it is reached.

In order to completely define the state of a system it is not necessary to define all the properties of the system; as only a certain number of properties can be varied independently. This number depends on the nature of the system.

Once these minimum number of macroscopic properties are fixed, others automatically have definite values. The state of the surroundings can never be completely specified; fortunately it is not necessary to do so.

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