4.2.1 Lattice Enthalpy

The Lattice Enthalpy of an ionic solid is defined as the energy required to completely separate one mole of a solid ionic compound into gaseous constituent ions. For example, the lattice enthalpy of NaCl is 788 kJ mol–1.

This means that 788 kJ of energy is required to separate one mole of solid NaCl into one mole of Na+ (g) and one mole of Cl (g) to an infinite distance.

This process involves both the attractive forces between ions of opposite charges and the repulsive forces between ions of like charge.

The solid crystal being three-dimensional; it is not possible to calculate lattice enthalpy directly from the interaction of forces of attraction and repulsion only. Factors associated with the crystal geometry have to be included.

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