4.1.4 Formal Charge

Lewis dot structures, in general, do not represent the actual shapes of the molecules. In case of polyatomic ions, the net charge is possessed by the ion as a whole and not by a particular atom.

It is, however, feasible to assign a formal charge on each atom. The formal charge of an atom in a polyatomic molecule or ion may be defined as the difference between the number of valence electrons of that atom in an isolated or free state and the number of electrons assigned to that atom in the Lewis structure.

It is expressed as :

The counting is based on the assumption that the atom in the molecule owns one electron of each shared pair and both the electrons of a lone pair. Let us consider the ozone molecule (O3). The Lewis structure of O3 may be drawn as :

The atoms have been numbered as 1, 2 and 3. The formal charge on:

Hence, we represent O3 along with the formal charges as follows:

We must understand that formal charges do not indicate real charge separation within the molecule. Indicating the charges on the atoms in the Lewis structure only helps in keeping track of the valence electrons in the molecule.

Formal charges help in the selection of the lowest energy structure from a number of possible Lewis structures for a given species. Generally the lowest energy structure is the one with the smallest formal charges on the atoms. The formal charge is a factor based on a pure covalent view of bonding in which electron pairs are shared equally by neighbouring atoms.

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