12.8.4 Differential Extraction

When an organic compound is present in an aqueous medium, it is separated by shaking it with an organic solvent in which it is more soluble than in water.

The organic solvent and the aqueous solution should be immiscible with each other so that they form two distinct layers which can be separated by separatory funnel. The organic solvent is later removed by distillation or by evaporation to get back the compound.

Differential extraction is carried out in a separatory funnel as shown in Figure. If the organic compound is less soluble in the organic solvent, a very large quantity of solvent would be required to extract even a very small quantity of the compound.

The technique of continuous extraction is employed in such cases. In this technique same solvent is repeatedly used for extraction of the compound.

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